Palladium(II) Complex of the 5-Hydroxypyridine-2-carbaldehyde N(4)-ethylthiosemicarbazone: Synthesis and Characterization

Yadav, Pravesh; Bhattrai, Laxman; Mehta, Pramod K.

doi:10.3126/jncs.v28i0.8040

Cited by 2 publications

(2 citation statements)

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“…The N-Ni-N and O-Ni-O bond angles range from 114.5 to 127.1 and 109.8 to 142.0 , respectively ( Table 2). In the vast majority of cases, complexes with a Ni(k 2 -N,O-L) 2…”

Section: X-ray Crystallographymentioning

confidence: 99%

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Synthesis and characterisation of κ²-N,O-oxazoline-enolate complexes of nickel(ii): explorations in coordination chemistry and metal-mediated polymerisation

2019

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The synthesis and characterisation (UV-Vis, IR, X-ray diffraction, etc.) of a series of Ni(II) complexes derived from both known and novel 2-acylmethyl-2-oxazolines (2a-g: i.e., (Z)-1-R-2-(4,4 0 -dimethyl-2 0 -oxazolin-These Ni materials (3a-g) represent the first group 10 metal complexes of this ligand class. All derivativesen-1-ate formed via proton loss from 2. The air-and moisture-stable metal complexes feature a less typical distorted seesaw-shaped disposition of binding atoms around the metal centre for six structurally characterised (X-ray) examples. Preliminary investigations indicate that 3a (R ¼ -Ph) is a useful catalysts for olefin polymerisation in the presence of alkylaluminum reagents. Scheme 1 Azole heterocycles: 1,3-oxazole (top, left); 1,3-benzoxazole (top, middle); 4,5-dihydro-1,3-oxazole (i.e., 2-oxazoline: top, right); 2-acylmethyl-2-oxazoline (A: bottom; enol tautomer shown).(2) { Reduced yields were noted employing [Ni(OH 2 ) 6 ](NO 3 ) 2 or [Ni(OH 2 ) 6 ]Cl 2 .This journal is a Polymerisation conditions: 1 h at 60 C; 20 mmol of 3a in 2 mL of C 7 H 8 ; 3 mL (2.7 g; 0.026 mol) of styrene in 7 mL C 7 H 8 . This journal is

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“…The N-Ni-N and O-Ni-O bond angles range from 114.5 to 127.1 and 109.8 to 142.0 , respectively ( Table 2). In the vast majority of cases, complexes with a Ni(k 2 -N,O-L) 2…”

Section: X-ray Crystallographymentioning

confidence: 99%

“…20.657 (4) 23.418 (2) 14.4705 (16) 16.2988 (9) 20.210 (2) 19.0410 (8) (9) 140.61 (6) 141.83 (5) 137.71 (5) 138.36 (5) 123.24 (7) O(3)-Ni(1)-N (2) 92.44 (10) 92.89 (6) 93.04 (5) 93.18 (5) 92.11 (5) 92.62 (8)…”

Section: Composition Havementioning

confidence: 99%

Synthesis and characterisation of κ²-N,O-oxazoline-enolate complexes of nickel(ii): explorations in coordination chemistry and metal-mediated polymerisation

2019

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Palladium(II) complexes of 5-substituted isatin thiosemicarbazones: Synthesis, spectroscopic characterization, biological evaluation and in silico docking studies

Munikumari¹,

Konakanchi

Nishtala

et al. 2019

Synthetic Communications

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Palladium(II) Complex of the 5-Hydroxypyridine-2-carbaldehyde N(4)-ethylthiosemicarbazone: Synthesis and Characterization

Abstract: The novel complex of 5-hydroxypyridine-2-carbaldehyde N(4)

Cited by 2 publications

References 10 publications

Synthesis and characterisation of κ²-N,O-oxazoline-enolate complexes of nickel(ii): explorations in coordination chemistry and metal-mediated polymerisation

Synthesis and characterisation of κ²-N,O-oxazoline-enolate complexes of nickel(ii): explorations in coordination chemistry and metal-mediated polymerisation

Palladium(II) complexes of 5-substituted isatin thiosemicarbazones: Synthesis, spectroscopic characterization, biological evaluation and in silico docking studies

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Palladium(II) Complex of the 5-Hydroxypyridine-2-carbaldehyde N(4)-ethylthiosemicarbazone: Synthesis and Characterization

Abstract: The novel complex of 5-hydroxypyridine-2-carbaldehyde N(4)

Cited by 2 publications

References 10 publications

Synthesis and characterisation of κ2-N,O-oxazoline-enolate complexes of nickel(ii): explorations in coordination chemistry and metal-mediated polymerisation

Synthesis and characterisation of κ2-N,O-oxazoline-enolate complexes of nickel(ii): explorations in coordination chemistry and metal-mediated polymerisation

Palladium(II) complexes of 5-substituted isatin thiosemicarbazones: Synthesis, spectroscopic characterization, biological evaluation and in silico docking studies

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Synthesis and characterisation of κ²-N,O-oxazoline-enolate complexes of nickel(ii): explorations in coordination chemistry and metal-mediated polymerisation

Synthesis and characterisation of κ²-N,O-oxazoline-enolate complexes of nickel(ii): explorations in coordination chemistry and metal-mediated polymerisation