2013
DOI: 10.1016/j.tsf.2013.04.119
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Palladium nanoparticles supported on reduced graphene oxide: Facile synthesis and highly efficient electrocatalytic performance for methanol oxidation

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Cited by 32 publications
(23 citation statements)
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“…There have been reports of chemically reduced GO by ultra-high vacuum heat [76], chemical treatments (with hydrazine/hydrazine derivatives [77] or high-concentration alkaline solution [78], which may lead some disadvantages such as considered to be dangerous substances labeled and required special equipments. A promising, green, efficient, inexpensive and rapid method based on electrochemistry to produce electrochemically reduced graphene oxide (ERGO) has been introduced [79][80]. Moreover, due to the stability of film on the electrode surface, time saving of fabrication and more excellent physic-chemical properties than pure GO and pure ERGO, the GO-ERGO nanocomposites was reported in recent time [81][82].…”
Section: Page 18 Of 72mentioning
confidence: 99%
“…There have been reports of chemically reduced GO by ultra-high vacuum heat [76], chemical treatments (with hydrazine/hydrazine derivatives [77] or high-concentration alkaline solution [78], which may lead some disadvantages such as considered to be dangerous substances labeled and required special equipments. A promising, green, efficient, inexpensive and rapid method based on electrochemistry to produce electrochemically reduced graphene oxide (ERGO) has been introduced [79][80]. Moreover, due to the stability of film on the electrode surface, time saving of fabrication and more excellent physic-chemical properties than pure GO and pure ERGO, the GO-ERGO nanocomposites was reported in recent time [81][82].…”
Section: Page 18 Of 72mentioning
confidence: 99%
“…The sharp peak at 1740 cm −1 correspond to (C=O) stretching of (−COOH) on the surface [77], and the strong absorption peak at approximately 1630 cm −1 is due to the stretching vibration of carbon backbone (C=C/C−C) [78,79]. In addition, the three absorption bands located at 1397, 1225, and 1060 cm −1 are assigned to stretching vibrations of (C−OH), (C−O−C) and (C−O), correspondingly [76,80]. In HRG spectra obtained from the reduction of GO in hydrazine monohydrate (Figure 3b), the broad band around 1214 cm −1 corresponds to (C−OH) stretching vibration and weak peak around 1634 cm −1 is related to (C=C) group owing to the skeletal aromatic vibration.…”
Section: Thermogravimetric Analysis (Tga)mentioning
confidence: 99%
“…Meanwhile, absorption band at around 580 cm −1 could be due to different oxides of manganese [85]. (Figure 3a) exhibits an intensive broad peak around 3430 cm −1 assigned to hydroxyl groups (O-H) stretching vibrations of (-COOH) groups and water molecules [76]. The sharp peak at 1740 cm −1 correspond to (C=O) stretching of (−COOH) on the surface [77], and the strong absorption peak at approximately 1630 cm −1 is due to the stretching vibration of carbon backbone (C=C/C−C) [78,79].…”
Section: Thermogravimetric Analysis (Tga)mentioning
confidence: 99%
“…The FTIR spectrum of graphite oxide exhibits an intensive broad peak of O\ \H stretching vibrations at about 3393 cm − 1 , and several bands at 1719, 1574, 1215 and 1044 cm −1 assigned to C_O, C_C, (C\ \O) epoxy and (C\ \O) alkoxy groups, respectively (Fig. 4a) [33]. The comparison of FT-IR spectra of graphite oxide and Pd NPs/rGO clearly shows that chemical changes occurred during Pd NPs deposition using ultrasonication.…”
Section: Preparation and Characterization Of Pd Nps/rgo Nanocompositementioning
confidence: 99%
“…The FTIR spectrum is dominated by a broad band at~1636 cm −1 due to C_C stretching modes, suggesting partial restoration of the aromatic network during the chemical process (Fig. 4b) [33].…”
Section: Preparation and Characterization Of Pd Nps/rgo Nanocompositementioning
confidence: 99%