Palladium(ii)-complexes of bi- and tri-dentate phosphine ligands: precursor for palladium–phosphorous nanoparticles and activity towards Suzuki–Miyaura coupling

Abstract

The crystalline Pd7P3 and Pd3P0.8 nanoparticles (NPs) formed when palladium(II)-complexes (1 and 2) of (P,N) ligand [3-(diphenylphosphino)propan-1-amine] L1 and (P,N,O–) ligand [2-(((3-(diphenylphosphino)propyl)imino)-(phenyl)methyl)phenol] L2 were thermolyzed in a mixture of oleylamine...

Fabrication of thiosemicarbazone-based Pd(ii) complexes: structural elucidations, catalytic activity towards Suzuki–Miyaura coupling reaction and antitumor activity against TNBC cells

“…Bulky dialkylbiaryl and triarylphosphines continue to be the most employed ligands for cross-coupling processes, followed by N-heterocyclic carbenes (NHCs). [39][40][41][42][43][44] Several palladium complexes containing pincer-type ligands have been found to be effective catalysts for C-C bond formation reactions. However, there are some reports of heterocyclic thiosemicarbazonebased Pd(II) complexes as catalysts in the SMC reaction.…”