Palladiumdichloride (ferrocenylethynyl)phosphanes and their use in Pd-catalyzed Heck–Mizoroki- and Suzuki–Miyaura carbon–carbon cross-coupling reactions

Electron‐Transfer Studies of trans‐Platinum Bis(acetylide) Complexes

“…[52][53][54][55] The higher coupling constants for electron-withdrawing groups than for electron-donating ones indicate an increased s character for the phosphorus lone pair. [53] Furthermore, the 31 P- 77 Se coupling constants are affected by the steric properties of the substituents at the phosphorus atom.…”

Fundamental study of (ferrocenylethynyl)phosphines: Correlation of steric and electronic effects in C,C cross-coupling reactions

“…High resolution-ESI-TOF mass-spectrometry and single crystal X-ray structure analysis (6e, 6f, 7b and 7c) were additionally carried out. The electrochemical behavior of the newly prepared compounds (cyclic voltammetry (CV) (3, 4, 6 and 7), square wave voltammetry (SWV) (6, 7), linear sweep voltammetry (LSV) (7), UVeVis/NIR spectroscopy (280e3000 nm) and in situ IR spectroscopy (7f)) is discussed as well.…”

Ferrocenyl phosphane nickel carbonyls: Synthesis, solid state structure, and their use as catalysts in the oligomerization of ethylene

“…The steric demand of a phosphane ligand can be expressed with the commonly used concept of the Tolman cone angle [47,52]. The Tolman cone angle allows to evaluate the catalytic activity of organometallics, as described elsewhere [52][53][54].…”

“…The Tolman cone angle allows to evaluate the catalytic activity of organometallics, as described elsewhere [52][53][54]. The cone angles were calculated to 167 (3 0 ), 169 (3 00 ), 180 (4 with P1), 162 (4 with P2), 166 (6b 0 with P1), 170 (6b 0 with P2), 166 (6b 00 ), 163 (7 with P1), and 153°(7 with P2) ( Table 3) using the program STERIC [55,56] implying larger cone angles than PPh 3 (145°) [47].…”