This work presents a triboelectric nanogenerator (TENG) fabrication using polytetrafluoroethylene, aluminum foil, and cellulose paper. Mechanical interactions lead to atomic defects that stimuli the delocalized electrostatic charge carriers and kinetic energy. The addition of ionic salt’s microdroplets improved the TENG’s performance. Eventually, surface charge activities have escalated the electrical signals. Further, studied spontaneously increased charge transport performance at the steady-state condition in the presence of NaCl ionic droplets. We considered that these ionic activities actively participated in detecting salt ions.