Paper Chromatographic Analysis of Urethan Derivatives of Saturated Aliphatic Alcohols.

Attaway, J. A.; Wolford, R. W.; Alberding, G. E.; Edwards, G. J.

doi:10.1021/ac60186a026

Cited by 15 publications

(3 citation statements)

References 9 publications

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“…The rea-gents used include phenylhydrazine hydrochloride, 1% in water, freshly prepared for each set of samples; aluminum oxide, Merck chromatographic grade; hydroxide of Hyamine 10X (Rohm & Haas, Reg. Trade Mark), 1 molar solution in methanol as used in preparation of samples for scintillation counting (available from Packard Instrument Co., Lagrange, 111. ); crystalline nitrofurazone standard (Hess & Clark).…”

Section: Methodsmentioning

confidence: 99%

Orange Essence Analysis, Identification of Alcohols and Volatile Organic Acids from Natural Orange Essence

Attaway¹,

Wolford²,

Alberding³

et al. 1964

J. Agric. Food Chem.

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Alcohols and volatile organic acids were isolated from natural orange essence and identified. The alcoholic constituents were removed from carbonyl-free aqueous essence by solvent extraction and column chromatography, while the organic acids were separated by steam distillation. Programmed temperature gas chromatography (PTGC), infrared analysis, and paper chromatography of the alcohols and alcohol derivatives, and PTGC and paper chromatography of the acids furnished confirmations of component identities. The following alcohols and acids were found in natural orange essence: methanol, ethanol, n-propanol, isobutanol, n-butanol, isopentanol, n-pentanol, n-hexanol, 3-hexen-1 -01, linalool, n-octanol, terpinen-4-01, n-nonanol, a-terpineol, n-decanol, citronellol, acetic acid, propionic acid, butyric acid, caproic acid, and capric acid. The presence of the following alcohols and acids was indicated but not confirmed: isohexanol, methyl heptenol, 2-nonano1, nerol, geraniol, carveol, isovaleric acid, valeric acid, isocaproic, and caprylic acid.N RECEST YEARS, the use of chroma-

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Section: Methodsmentioning

confidence: 99%

Orange Essence Analysis, Identification of Alcohols and Volatile Organic Acids from Natural Orange Essence

Attaway¹,

Wolford²,

Alberding³

et al. 1964

J. Agric. Food Chem.

Self Cite

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show abstract

“…were chromatographed in uncombined form on paper (72,660,710,1176,1632,1685). Monohydric alcohols were first converted to monoalkyl sulfates (178), mercuric acetate addition compounds (1013, 1759), or urethan derivatives (52). Cellulose powder columns have been used for both mono- (1537) and polyhydroxy (405) compounds.…”

Section: Alcohols Only Polyhydric Alcoholsmentioning

confidence: 99%

“…Analogous results have been obtained with commercial adsorbent-coated filter papers (749, 1467). Paper was also impregnated with petroleum jelly (52), polymethylsiloxane (1496), paraformaldehyde (684), nitrocellulose, 1-bromonaphthalene, etc. ( 1184), but untreated filter paper could be used for saponins (856,1626), terpene alcohols, aldehydes (603), and acids (1180).…”

Section: Carbohydratesmentioning

confidence: 99%

Chromatography

Heftmanń¹

1964

Anal. Chem.

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Fortschritte auf dem Gebiet der Lipoid‐Analyse III: Papier‐Chromatographie, Teil 2

1970

Fette, Seifen, Anstrichm.

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Paper Chromatographic Analysis of Urethan Derivatives of Saturated Aliphatic Alcohols.

Cited by 15 publications

References 9 publications

Orange Essence Analysis, Identification of Alcohols and Volatile Organic Acids from Natural Orange Essence

Orange Essence Analysis, Identification of Alcohols and Volatile Organic Acids from Natural Orange Essence

Chromatography

Fortschritte auf dem Gebiet der Lipoid‐Analyse III: Papier‐Chromatographie, Teil 2

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