Paper Chromatographic Separation, Identification, and Determination of Diglycerols.

Siegel, H. S.; Bullock, A.B.; Carter, G. B.

doi:10.1021/ac60209a054

Cited by 8 publications

(2 citation statements)

References 17 publications

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“…Other metameric configurations are also possible such as cis-2,5-, cis-2,6-, and trans-2,6-bis(hydroxymethyl )-pdioxane. Samples of ~'~-and a,fl'-diglycerol separated by paper chromatography were obtained from Siegel (6). GLC of the TMS ethers of these compounds individually and in mixtures showed that a,fl-diglycerol is eluted before the a,a'-isomer and appears as a shoulder on peak No.…”

Section: Resultsmentioning

confidence: 99%

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Chromatographic analysis of polyglycerols and their fatty acid esters

Sahasrabudhe¹

1967

J Americ Oil Chem Soc

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Polyglycerols and their fatty acid esters have been analyzed by gas-liquid chromatography (GLC) as trimethylsilyl ether derivatives. Linear diglyccrols and triglycerols were isolated from commercial polyglycerols by vacuum distillation. Mono-and di-fatty acid esters were synthesized in the laboratory. Two isomers of diglycerol have been separated and identified. GLC analysis was carried out on columns packed with 3% JXR on Gas Chrom Q. Response factors for diglycerol and triglycerol relative to glycerol have been established. Commercial polyglycerol esters are shown to be mixtures of glycerol, free fatty acids, mono-and diglyeerides, and mono-fatty acid esters of diglycerol and triglycerol. Separation of free polyglycerols and their esters is also demonstrated by thin-layer chromatography on Silica Gel-G containing 4.0% boric acid.

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Section: Resultsmentioning

confidence: 99%

“…p OLYGLYCEROLS ARE PREPARED by acid or basecatalyzed condensation of glycerol. Linear and cyclic polyglycerols containing two and more glycerol units are described by several workers (1)(2)(3)(4)(5)(6)(7)(8)(9)(10)(11)(12)(13). It has been demonstrated that polyglycerols readily form esters with fatty acids (2).…”

Section: Introductionmentioning

confidence: 99%

Chromatographic analysis of polyglycerols and their fatty acid esters

Sahasrabudhe¹

1967

J Americ Oil Chem Soc

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Zur Kenntnis der Polyglycerinfettsäureester

Stenzel

Franzke

1977

Nahrung

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Polyglycerinfettsiiureester (PGFE) haben in den letzten Jahren als Emulgatoren wegen ihrer vielfatigen Anwendungsm6glichkeiten zunehmende Bedeutung ffir die Lebensmittelindustrie erlangt. Sie werden durch Umsatz von Polyglycerin (PG) mit FettsBuren bzw. Fetten hergestellt. I. Polyglycerin (PG)Unter PG werden die linearen Kondensationsprodukte von Glycerin (Propantrio1-1,~,3) wrstanden. Abb. I zeigt die allgemeine Strukturformel. Aus der Literatur sind Kondensationsprodukte bekannt. in denen bis zu 40 Glycerinmolekfile linear verknfipft sind (P24). Di-und

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Übersichtsartikel. Synthese, Charakterisierung und Applikation von Polyglycerolen und Polyglycerolfettsäureestern

Behrens

Mieth

1984

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The current state of knowledge in the field of synthesis and properties of polyglycerols and polyglycerol fatty acid esters is presented. Alternatives for the analytical characterization of these families by means of physico-chemical methods, with special reference to chromatography and spectroscopy, are described. Furthermore, the use of polyglycerol fatty acid esters as food additives is considered from the view-points of the physiology of nutrition and of processing technology.

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Paper Chromatographic Separation, Identification, and Determination of Diglycerols.

Cited by 8 publications

References 17 publications

Chromatographic analysis of polyglycerols and their fatty acid esters

Chromatographic analysis of polyglycerols and their fatty acid esters

Zur Kenntnis der Polyglycerinfettsäureester

Übersichtsartikel. Synthese, Charakterisierung und Applikation von Polyglycerolen und Polyglycerolfettsäureestern

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