Paper microzone plates integrating Natural Deep Eutectic Solvents: Total phenolic compounds and antioxidant capacity as performed by nature

Espino, Magdalena; Fernández, María de los Ángeles; Silva, María Fernanda; Gomez, Federico José Vicente

doi:10.1016/j.microc.2020.105296

Cited by 12 publications

(1 citation statement)

References 24 publications

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“…High solubilization capacity, biodegradability, tunable properties, safety, reusability, simple preparation, high availability, and low-cost components make NADES excellent candidates for analytical applications . These solvents are formed by mixtures of common cellular constituents such as sugars, amino acids, organic acids, and choline derivatives, whose main driving forces are hydrogen bonds, with melting points hundreds of degrees lower than those of the constituents. , NADES stand out for being design solvents with tunable physicochemical properties due to the large number of potential combinations of their components (∼10 6 ). They are also low-cost and require simple preparation procedures, enabling their synthesis at the time of use. , …”

Section: Introductionmentioning

confidence: 99%

Native Fluorescent Natural Deep Eutectic Solvents for Green Sensing Applications: Curcuminoids in Curcuma longa Powder

Lorenzetti

Vidal

Silva

et al. 2021

ACS Sustainable Chem. Eng.

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Natural deep eutectic solvents are a trending topic in Green Chemistry. These solvents present high solubilization capacity, reusability, tunable properties, simple preparation, biodegradability, safety, high availability, and low cost, making them excellent candidates for analytical applications. In this work, a new family of fluorescent eutectic systems is described, with the fluorescence property being unknown and unused so far. For this purpose, a novel preparation method using an ultrasound probe was employed, by means of an innovative single-step procedure, that included the preparation of FCH (fructose, citric acid, and water, 1:1:5 molar ratio) and the extraction/determination of curcuminoids from Curcuma longa powder. This methodology was successfully carried out by employing a portable and inexpensive 3D-printed fluorometer and a smartphone. In this way, extraction efficiencies between 90 and 106%, relative to the NIST reference method, were obtained in just 3.40 min. Besides, the greenness of the new methodology was evaluated by employing the AGREE metric, showing that the developed approach is >2.5 times greener than previously published works for curcuminoid determination. This groundbreaking procedure is robust, versatile, and simple to implement, does not require sophisticated apparatus or instruments in the detection step, and, mainly, agrees with Green Analytical Chemistry (GAC) principles.

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