In this paper, we consider a scenario of spontaneous baryogenesis in a framework of warm quintessential inflation where the residual inflaton field, left out after warm inflation, plays the role of quintessence field at late times and is coupled to a non-conserved baryonic current. Assuming a four fermion (B − L) violating effective interaction, we have demonstrated that the required baryon asymmetry can be produced successfully in this case. We show that the post-inflationary evolution, with the underlying scalar field potential, V (φ) = V 4 0 exp (−αφ n /M 4 Pl ), n > 1 well suited to warm inflation, exhibits scaling behaviour soon after a brief kinetic regime. We show that the coupling of the scalar field to massive neutrino matter can give rise to exit from the scaling regime to cosmic acceleration at late times as massive neutrinos turn non-relativistic. The proposed model is shown to successfully describe the cosmic history from inflation to late-time acceleration, with the evolution independent of initial conditions, along with the generation of baryon asymmetry during the post-inflationary era.