Paradoxes and paradigms: are maleimides antiaromatic, aromatic, or neither?

Ptaszek, Marcin; Liebman, Joel Fredric

doi:10.1007/s11224-023-02233-w

Struct Chem

2023

DOI: 10.1007/s11224-023-02233-w

|View full text |Cite

Paradoxes and paradigms: are maleimides antiaromatic, aromatic, or neither?

Marcin Ptaszek,

Joel Fredric Liebman

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

References 54 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Anti-aromaticity Increases Single-Molecule Junction Conductance

Zhang,

Zhao,

Zheng

2024

J. Phys.: Conf. Ser.

View full text Add to dashboard Cite

Using a scanning tunneling microscope-based break-junction technique, we assessed the conductance of single-molecule junctions formed with three distinct molecular wires, each featuring a cyclic five-membered ring: furan, cyclopentanone or cyclopentadiene. We found that the conductance of these three wires correlates with their aromaticity; the non-aromatic cyclopentadienone derivative exhibits the highest conductance, while the most aromatic furan in this series displays the lowest conductance. Additionally, the lower HOMO-LUMO gap of anti-aromatic compounds may also contribute to this effect. This discovery aids in understanding the influence of molecular structure on conductive properties and provides crucial insights for the design and optimization of molecular electronic devices.

show abstract

Anti-aromaticity Increases Single-Molecule Junction Conductance

Zhang,

Zhao,

Zheng

2024

J. Phys.: Conf. Ser.

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Paradoxes and paradigms: are maleimides antiaromatic, aromatic, or neither?

Cited by 1 publication

References 54 publications

Anti-aromaticity Increases Single-Molecule Junction Conductance

Anti-aromaticity Increases Single-Molecule Junction Conductance

Contact Info

Product

Resources

About