1980
DOI: 10.1021/ed057p373
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Paramagnetism and color of liquid oxygen: A lecture demonstration

Abstract: When liquid nitrogen is poured between the poles of a powerful magnet, the liquid is not held in the pole gap. When liquid oxygen is poured between the poles of the magnet, some of the liquid is held in the pole gap until the liquid evaporates. This demonstration also displays the characteristic blue color of liquid oxygen. MaterialsLiquid nitrogen (5-8 1) 02 gas (cylinder with pressure regulator) 2 Dewar flasks (11 capacity) Large test tube (38 mm o.d. X 300 mm long) Ring stand and clamp to hold the large tes… Show more

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Cited by 8 publications
(10 citation statements)
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“…Because Gd3+ is slightly larger than Y3+, we would expect that the lattice parameter, a (the length of the side of the cubic unit cell), would increase with increasing gadolinium content. This trend is clearly seen in the data presented in Table 1 and graphically depicted in Figure 4. 2 Many students have difficulty understanding the difference between a single-phase solid solution compound, such as Yi.6Gdi,5Fe50i2, where there is a 50% probability that the atom on the rare earth site is Y or Gd, and a physical two-phase mixture containing equal amounts of Y3Fe50i2 and Gd3Fe5Oi2.…”
Section: Suggested Use In Labsupporting
confidence: 54%
“…Because Gd3+ is slightly larger than Y3+, we would expect that the lattice parameter, a (the length of the side of the cubic unit cell), would increase with increasing gadolinium content. This trend is clearly seen in the data presented in Table 1 and graphically depicted in Figure 4. 2 Many students have difficulty understanding the difference between a single-phase solid solution compound, such as Yi.6Gdi,5Fe50i2, where there is a 50% probability that the atom on the rare earth site is Y or Gd, and a physical two-phase mixture containing equal amounts of Y3Fe50i2 and Gd3Fe5Oi2.…”
Section: Suggested Use In Labsupporting
confidence: 54%
“…Our method of preparing liquid oxygen follows that of Shakhashiri , . We collect about 20−50 mL of liquid oxygen and direct it in a stream past a 0.25 T permanent magnet.…”
Section: Demonstrationsmentioning
confidence: 99%
“…The observation that, under other conditions (as the product of a chemical reaction), oxygen emits red light, provides further amazement. Over the years, several methods of demonstrating the paramagnetic and optical properties of oxygen have been published in this Journal . Using these demonstrations is an elegant way of introducing or reinforcing the concepts of molecular orbital (MO) theory.…”
mentioning
confidence: 99%
“…In this Journal , one of the first published articles along these lines was likely H. P. Cady’s 1931 multipage treatise on Liquid Air . Although today’s more prudent safety standards preclude many of Cady’s demonstrations from being commonplace, his description of the “distinctly magnetic” nature of liquid oxygen in the presence of a “strong electromagnet” ultimately contributed to the genesis of Shakhashiri’s procedure as well as others used in modern illustrations of oxygen’s paramagnetism . Although experienced chemical demonstrators do still generate sizable amounts (ca.…”
Section: Introductionmentioning
confidence: 99%