The physical properties of oxygen, in particular, the
blue color of the liquid phase, the red glow of its chemiluminescence,
and its paramagnetism as shown by the entrapment or deflection of
liquid oxygen by a magnetic field, can be investigated in a regular
school setting with hand-held spectrophotometers and digital cameras.
In college-level chemistry courses, the paramagnetic property often
serves as a dramatic illustration of the usefulness of molecular orbital
(MO) theory. However, MO treatment of oxygen molecules alone cannot
explain the observed photon absorptions and emissions. In fact, it
is the formation of oxygen dimers (O2)2 that accounts for the observed optical phenomena and is also
responsible for the “not-quite-right” degree of deflection
of the liquid stream of oxygen near a magnet. A review of experimental
and theoretical studies of O4 and (O2)2 suggests that the so-called one-photon-two-O2-molecule
mechanism be considered a one-photon-one-O2-dimer process.