This paper proposes a detection and classification method of recessive weakness in Superbuck converter through wavelet packet decomposition (WPD) and principal component analysis (PCA) combined with probabilistic neural network (PNN). The Superbuck converter presents excellent performance in many applications and is also faced with today’s demands, such as higher reliability and steadier operation. In this paper, the detection and classification issue to recessive weakness is settled. Firstly, the performance of recessive weakness both in the time and frequency domain are demonstrated to clearly show the actual deterioration of the circuit system. The WPD and Parseval’s theorem are utilized in this paper to feature the extraction of recessive weakness. The energy discrepancy of the fault signals at different wavelet decomposition levels are then chosen as the feature vectors. PCA is also employed to the dimensionality reduction of feature vectors. Then, a probabilistic neural network is applied to automatically detect and classify the recessive weakness from different components on the basis of the extracted features. Finally, the classification accuracy of the proposed classification algorithm is verified and tested with experiments, which present satisfying classification accuracy.