Although awareness of the phenomenon of temperature separation in Ranque-Hilsch vortex tubes dates back at least nine decades, some mystery surrounding the phenomenon remains to this day. These devices split an incoming stream of fluid into two streams—one with a greater total temperature than the incoming fluid and the other with a lower total temperature. This temperature separation is accomplished with no moving parts and no external sources of energy including heat transfer to or from the device. In attempts to understand the physics of the temperature separation, previous researchers have characterized the effect through various inlet temperatures and pressures as well as various gases with different properties. Unfortunately, the findings documented in the literature are sometimes inconsistent indicating the possibility that previously uncontrolled properties and flow conditions govern temperature separation to an unappreciated degree. In the present research, two new flow characteristics are examined for their role in temperature separation—volumetric heat capacity, ρC_p, and nozzle velocity. In the present experiments with air, it was found that by matching nozzle velocity and ρC_p—even with disparate pressures, temperatures, Reynolds numbers, and Mach numbers—the resulting temperature separation curves are identical. This is the first known documentation of such a finding. The results suggest that nozzle velocity is fundamental to scaling the performance of a vortex tube, while the nozzle volumetric heat capacity is also relevant to its behavior.