Ram air turbines are used in the power generation systems of hypersonic vehicles, which can address the problem of the high power consumption of weapon systems. However, high incoming air temperatures can cause the turbine blades of power generation to ablate. At this point, the incoming air can no longer be used as a cooling source to cool the turbine blades. To prevent the ablation of the turbine blades of the hypersonic vehicle power generation, hydrocarbon fuel carried by the hypersonic vehicle itself is used to cool the turbine blades. Hence, hydrocarbon fuels under rotating conditions are investigated. The results show that the rotation leads to a strong pressure gradient that causes the density and dynamic viscosity of hydrocarbon fuel to increase dramatically. Compared to the static condition, the density and dynamic viscosity of the hydrocarbon fuel increase by a maximum of 65.1% and 405%, respectively, under the rotating condition. This leads to an obvious reduction in velocity. The comprehensive influence of the physical properties of the fuel, centrifugal force, and Coriolis force causes the convective heat transfer coefficient and Nusselt number of the channel to first increase and then decrease with the increase in the rotational speed. Compared to the static condition, the convective heat transfer coefficient and Nusselt number increase by a maximum of 69.7% and 45.6%, respectively, under the rotating condition. The critical rotational speed of the Nusselt number from rise to fall is 20,000 rpm for different inlet temperature conditions.