To cite this version:Loic Deyra, Alain Maillard, R Maillard, D Sangla, F Salin, et al.. Impact of BaB 2 O 4 growth method on frequency conversion to the deep ultra-violet. Solid State Sciences, Elsevier, 2015, 50, pp.97-100. 10 This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting proof before it is published in its final form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain. Czochralski and TSSG β-BBO crystals are compared for high power UV (266nm) in second harmonic generation. Impurities from flux decrease the efficiency of harmonic generation at high power (40%). Corresponding author : A Maillard, alain.maillard@univ-lorraine.fr
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Impact of BaBAbstract: In this article, we report how the growth method used for barium beta-borate β−BaB2O4 (BBO) impacts its high power second harmonic generation properties in the deep-UV. We compared a BBO crystal grown by flux (Top Seeded Solution Growth or TSSG) and a BBO crystal grown by the Czochralski (CZ) method. We first characterized their transparency properties, then we measured their single-pass second harmonic conversion efficiencies with both a low average power and a high average power nanosecond pulsed lasers. We show that both crystals have comparable linear absorption and conversion efficiencies at low power, whereas in a high power experiment, the CZ-grown BBO yields higher conversion efficiency than the TSSG grown BBO. With a 30 W, 150 kHz, 8ns green laser, the use of a CZ BBO led at best to a 40% increase in available average output power at 257 nm.Keywords: Borates, Nonlinear optical, Czochralski growth, Solution growth, Second harmonic generation.
IntroductionThe material machining industry has continuously looked to process more and more types of materials efficiently. For some of them such as silicon, glass, sapphire, the ultraviolet lasers (UV) were developed in order to increase the material absorption [1,2]. While UV lasers around 350 nm obtained by third harmonic generation (THG) are now commonly used in material processing, deep-UV lasers obtained by fourth harmonic generation (FHG) around 260 nm are still challenging to realize. The nonlinear material quality is a key parameter in order to reach high and stable conversion efficiency by reducing thermal dephasing and degradation effects. Beta-barium borate β-BaB2O4 (BBO) is a nonlinear crystal that has good properties for frequency conversion to the UV, such as a high nonlinearity or a short cut-off wavelength in the UV around 190nm [3]. It is available commercially, and is usually grown by top-seeded solution growth (TSSG) assisted with either a Na2O or NaF flux [4]. BBO can be also grown without flux by the Czochralski (CZ) method, but...