Parametric study and process modeling for metronidazole removal by rhombic dodecahedron ZIF-67 crystals

Abstract

Metronidazole (MNZ) is an extensively used antibiotic against bacterial infections for humans and farm animals. Prevention of antibiotics discharge is essential to prevent adverse environmental and health impacts. A member of metal–organic frameworks, zeolite imidazole framework-67 with cobalt sulfate precursor (ZIF-67-SO4) and exceptional physio-chemical properties was prepared via room temperature precipitation to adsorb MNZ. The study framework was designed by Box–Behnken Design to evaluate the effect of pH, ZIF-67-SO4 dose, and contact time on adsorption efficiency. The polynomial model fitted the adsorption system indicated the optimal condition for 97% MNZ removal occurs at pH = 7, adsorbent dosage = 1 g/L, and mixing time = 60 min. The model also revealed that the removal increased with contact time and decreased at strong pH. Equilibrium and kinetic study also indicated the adsorption of MNZ followed the intra-particle diffusion model and the Langmuir isotherm model with a qmax = 63.03 mg/g. The insignificant loss in removal efficacy in use-reuse adsorption cycles reflected the practical viability of ZIF-67-SO4.

Dopant-Induced Charge Redistribution on the 3D Sponge-like Hierarchical Structure of Quaternary Metal Phosphides Nanosheet Arrays Derived from Metal–Organic Frameworks for Natural Seawater Splitting

“…The molecular structure of the pristine ZIF-67 was investigated by a FT-IR spectrometry analyzer. As illustrated in Figure c, the characteristic stretching and bending modes of the imidazole ring were observed at the prominent vibrational bands in the range of 600–1500 cm –1 . The strong band at 422 cm –1 could be assigned to the Co–N stretch mode .…”

“…As illustrated in Figure 3c, the characteristic stretching and bending modes of the imidazole ring were observed at the prominent vibrational bands in the range of 600−1500 cm −1 . 47 The strong band at 422 cm −1 could be assigned to the Co−N stretch mode. 48 Also, the bands at 1577 and 2927 cm −1 were attributed to the stretching mode of C�N in 2-mim and C−H from the aromatic ring, respectively.…”