Multiwalled
carbon nanotubes (CNTs) are used as reinforcement in
epoxy modified with adduct, that is, block copolymer of carboxyl-terminated
butadiene acrylonitrile (CTBN) and diglycidyl ether of bisphenol A
(DGEBA). Microstructure analysis reveals uniform dispersion of a phase
with spherical morphology in a continuous phase. The mean diameter
of the spherical particles increased with CNT and adduct content.
At 30 wt % adduct, adding CNTs results in exceptional growth of spherical
particles. Loss factors in the first two modes were determined by
using free vibration test in cantilever mode. Significant increase
in loss factor is obtained for the epoxy nanocomposites modified with
30 wt % adduct and at all wt % CNTs (i.e., 0.5, 1, and 2.5). The vibration
damping mechanism in this nanocomposite is likely due to the relative
sliding of spherical particles during dynamic loads, which dissipates
energy. The reduction in the distance between spherical particles
as well as the reduction in the elastic modulus of continuous phase
facilitate relative sliding.