Parametric study of sweetening process of sour gas by Molybdenum oxide nanoparticles

Abstract

The purpose of this work is to study the application of nano-molybdenum oxide adsorbent in gas sweetening process. Experiments were made to evaluate the operating and geometrical parameters in the adsorption process. The process performance of H 2 S removal from methane gas on molybdenum oxide nanoparticles was defined as the ratio of final concentration of H 2 S on the initial concentration of H 2 S. The effects of operating conditions such as operating temperature, pressure, the size of nanoparticles, the amount of H 2 S concentration in feed stream, feed superficial velocity, and the bed length were studied in this paper. Different temperature values (65, 75, 85, 87 and 89 °C) and pressure values (10, 13, 16 and 19 bar) were applied on the adsorption bed with 19 cm length and 10 cm diameter. Two types of spherical and cylindrical nanoparticles were applied and the effect of different adsorbents diameters (54, 58, 73, 77 and 83 nm) on the process quality (C/C 0) was investigated. Also, the effect of initial concentration of H 2 S in the feed gas stream was surveyed. The optimum operating conditions for spherical and cylindrical types were the same, 16 bar and 85 °C. The adsorption capacity of 0.22 g H 2 S/g MoO 2 and 0.19 g H 2 S/g MoO 2 was achieved at the optimum conditions using nano-spherical and nano-cylindrical MoO 2 sorbent, respectively. Applying in our study two adsorption isotherms, the Langmuir and Freundlich isotherms, analysis of variance displayed a high coefficient of determination (R 2) value of 0.989 for the Freundlich isotherm, indicating the satisfactory adjustment of the experimental data. The results can be interesting for related industries and can be applicable in process optimization.

Prospects of Some Applications of Engineered Nanomaterials: A review

“…[39]. The application of nano-molybdenum oxide adsorbent in natural gas sweetening process (removal of H 2 S) has been demonstrated [40]. A comparative study has been performed on using carbon nanomaterials for SO 2 gas removing by adsorption [41].…”