We report a detailed analysis of the energy spectra, second-and high-order structure functions of velocity differences in superfluid 4 He counterflow turbulence, measured in a wide range of temperatures and heat fluxes. We show that the one-dimensional energy spectrum Exz(ky) (averaged over the xz-plane, parallel to the channel wall), directly measured as a function of the wall-normal wave-vector ky, gives more detailed information on the energy distribution over scales than the corresponding second-order structure function S2(δy). In particular, we discover two intervals of ky with different apparent exponents: Exz(ky) ∝ k −m C y for k k× and Exz(ky) ∝ k −m F y for k k×.Here k× denotes wavenumber that separate scales with relatively strong (for k k×) and relatively weak (for k k×) coupling between the normal-fluid and superfluid velocity components. We interpret these k-ranges as cascade-dominated and mutual friction-dominated intervals, respectively. General behavior of the experimental spectra Exz(ky) agree well with the predicted spectra [Phys. Rev. B 97, 214513 (2018)]. Analysis of the n-th order structure functions statistics shows that in the energy-containing interval the statistics of counterflow turbulence is close to Gaussian, similar to the classical hydrodynamic turbulence. In the cascade-and mutual friction-dominated intervals we found some modest enhancement of intermittency with respect of its level in classical turbulence. However, at small scales, the intermittency becomes much stronger than in the classical turbulence.