For the laser wakefield acceleration, suppression of beam energy spread while keeping sufficient charge is one of the key challenges. In order to achieve this, we propose bichromatic laser ionization injection with combined laser wavelengths of 2.4µm and 0.8µm for wakefield excitation and for triggering electron injection via field ionization, respectively. A laser pulse at 2.4µm wavelength enables one to drive an intense acceleration structure with relatively low laser power. To further reduce the requirement of laser power, we also propose to use carbon dioxide as the working gas medium, where carbon acts as the injection element. Our full three dimensional particle-in-cell simulations show that electron beams at the GeV energy level with both low energy spreads (around one percent) and high charges (several tens of picocoulomb) can be obtained by this scheme with laser parameters achievable in the near future.PACS numbers: 52.65. Rr, 41.75.Jv, 52.38.Kd, 41.85.Ar Ever since its invention, the laser wakefield accelerator (LWFA) has been considered as one of the most promising candidates of the next generation of accelerators 1 . Compared with conventional radio-frequency accelerators, a laser wakefield accelerator has the advantage of several orders higher acceleration gradient, meanwhile currently it has the drawbacks of relatively poor beam qualities. Great progresses has been made over the past years 2-7 . Nevertheless, to further improve the beam quality including the charge, peak energy, energy spread, and emittance is still one of the top priorities in the community in order to make the LWFA suitable for applications.There are mainly two ways of improving the output beam quality. One is improving the beam phase space distribution during the acceleration processes 8 , and the other is improving the injection processes at the very beginning of the acceleration 9-11 . Among the variety of injection schemes, the ionization-induced injection is found to be simple and effective [12][13][14][15][16][17][18][19][20] . By using different variations of this mechanism, electron beams with low emittances down to the nano-meter level [21][22][23] , or low energy spreads down to a few percent [24][25][26] were produced. Recently, a new ionization injection variation utilizing the beating of bichromatic lasers to produce subpercent energy spread is proposed 27 . In this scheme, the driver is a femtosecond laser pulse with two frequency components ω 1,2 , and the laser peak electric field amplitude evolves due to the dispersion difference of the two frequency components. The evolution length period of the electric field amplitude is The laser is square-wave-like bichromatic with wavelengths of 2.4 µm and 0.8 µm, and the ionization object is C 4+ . The solid line shows the ionization probability after one laser cycle when the combined electric field takes the form of E 10 cos(ωt) + 1 3 cos(3ωt) , and the dash-dot line shows that when it takes the form of E 10 sin(ωt) + 1 3 sin(3ωt) .which is typically in hundred microm...