In order to increase the comfort of vehicle passengers in specific vehicle categories, the heating of the passenger compartment is not provided by the heat from the engine driving the vehicle but by an additional heating device. The study examines the effect of auxiliary heaters that use liquid fuels to heat the passenger compartment of vehicles. The device was operated during the test with two different mixtures containing bioethanol (E30, E100) and the original motor gasoline (E10). It aimed to understand the effects of different fuels, particularly heating performance, operating time and emissions. Based on the results, as the ethanol content increases, the temperature of the device’s flame and heating air decreases. The experiments showed that in the case of E100 bioethanol, the average temperature measured in stable operating conditions was significantly lower than in the case of E10 motor gasoline. That suggests that an increase in the ethanol content reduces the heating performance. Another significant result of the study was that in the case of mixtures containing ethanol, a longer operating time is required to achieve the same amount of heat, which leads to additional fuel consumption. In addition, when using E100 bioethanol, the amount of harmful gases that are emitted increases significantly during the longer operating time. This observation can be important for evaluating the environmental impact and efficiency of vehicles.