Particularities of Radiation Defect Formation in Ceramic Barium Cerate

Khromushin, I.V.; Aksenova, T.I.; Tuseev, T.; Munasbaeva, K.K.; Ermolaev, Yu. V.; Ermolaev, V.N.; Seitov, A.

doi:10.1088/1757-899x/81/1/012037

Cited by 1 publication

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“…Thus, the effects of radiation on solids with a developed surface and the impact of adsorption processes on irradiated materials are new research fields in electronic and structural factors. The present research makes it possible to understand the role of free and localized charge carriers in elementary acts of catalysis and chemisorption and the ability of adsorbed molecules to serve as traps for electrons and holes, as compared with other trappings of structural defects or impurity atoms located on the surface [14][15][16][17]. With sufficient information on these factors, it is possible to generate effective systems with predicted physical and technological properties [18].…”

Section: Introductionmentioning

confidence: 99%

Radiation-stimulated adsorption processes on the surface of beryllium oxide

et al. 2022

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The paper presents the study results of photo and gamma radiation effect on the beryllium oxide (BeO) surface properties. Photoadsorption studies of О2 on BeO by the methods of infrared (IR) spectroscopy and manometry with a change in the temperature of preliminary annealing from 473 to 1073 K show that samples subjected to preliminary training at 473 K are most active. The maximum of adsorption activity on g-irradiated beryllium oxide is observed on the samples annealed at 673 K before the irradiation. The maximum of paramagnetic centers (PMCs) is also observed on samples annealed at this temperature. Comparison of electron paramagnetic resonance (EPR) and adsorption studies shows that absorption of H2 and O2 leads to the destruction of paramagnetic centers. It is assumed that, upon irradiation, adsorption centers with electron and hole modes are formed on the surface of BeO.

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