Over the past year we have initiated a study into the passive standoff detection of radiological materials by Fouriertransform infrared (FTIR) radiometry. The preliminary work has shown that a number of radiological materials have an infrared signature in the 8 -14 µm thermal infrared region. As well, through a series of simulations using the MODTRAN4 atmospheric transmission model, we have shown that these materials may potentially be detected at standoff distances of several kilometres. In this paper we present some results of our current work that focus on recent new measurements of spectral signatures, including the uranium oxides UO 2 and UO 3 . Preliminary results from a measurement campaign held at Defence Research and Development Canada -Valcartier this year are also presented which address the passive detection of radiological materials in the field at standoff distances of 10 -60 m. These results are analysed in view of determining the potential for measuring nuclear products with a passive standoff FTIR technique.