We prove the unirationality of many Del Pezzo surfaces of degree 2 with rational double points. Over perfect fields, we find all except three RDP Del Pezzo surfaces are non-minimal and thus unirational. Even if not perfect, we obtain a condition of the unirationality that was proved in smooth Del Pezzo surfaces of degree 2 by Salgado, Testa and Várilly-Alvarado. Using these results, we prove the unirationality over finite fields with at least 9 elements.