“…Polymer films used as dielectric materials are characterized by their excellent properties such as high insulating resistance, low dielectric loss, high breakdown strength, good mechanical properties, perfect processability, and low cost, which are completely different from dielectric ceramics . The most widely used dielectric polymers are polypropylene (PP), polyethylene (PE), polystyrene (PS), poly(methyl methacrylate) (PMMA), poly(vinylidene fluoride) (PVDF), epoxy resin, and polyimide (PI) . However, most of them have low dielectric constant (ε), which limits their applications as energy‐storage dielectric materials in capacitors, piezo‐ and pyroelectric sensors, and field‐activated actuators.…”