“…The most well‐known and exploited route to β‐enaminones 3 involves the direct condensation of β‐dicarbonyl compounds 1 with amines 2 in refluxing aromatic hydrocarbons with azeotropic removal of water. Other improved procedures have also been subsequently reported which include the reaction of amines 2 with β‐dicarbonyl compounds 1 supported on AcOH under ultrasound, CoCl 2 .6H 2 O, CAN, microwave irradiation, TMSTf, Zn(OAc) 2 .2H 2 O, K 2 HPO 4 , InBr 3 , [(PPh 3 )AuCl]/AgOTf, silica gel, HClO 4 ⋅SiO 2 , Bi(TFA) 3 , NaAuCl 4 , ZrOCl 2 .8H 2 O, catalyst free, solvent free‐ grinding, NaHSO 4 /SiO 2 , LiHSO 4 /SiO 2 , Ni(OAc) 2 , copper catalyst, CuBr 2 /L 2 /pyrrolidine, CuI, mesoporous alumina sulphuric acid, water‐lactic acid, L‐proline, silica‐supported antimony(III) chloride, clays, LaCl 3 , MW/K‐10 or MW/KSF, DMF/DMA, Ag/HMMS, PPA‐SiO 2 , ionic liquids based, nano fibrous silica sulphuric acid (KCC‐1‐SA) . Unfortunately many of these processes are have major or minor limitations such as drastic reaction conditions, prolonged reaction time, high temperature, low yields and tedious work‐up procedures.…”