PbTeB4O9: a lead tellurium borate with unprecedented fundamental building block [B4O10] and large birefringence

Zhang, Ruonan; Tudi, Abudukadi; Yang, Xia; Wang, Xuping; Yang, Zhihua; Han, Shujuan; Pan, Shilie

doi:10.1039/d3cc05382b

Chem. Commun.

2024

DOI: 10.1039/d3cc05382b

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PbTeB₄O₉: a lead tellurium borate with unprecedented fundamental building block [B₄O₁₀] and large birefringence

Ruonan Zhang,

Abudukadi Tudi,

Xia Yang

et al.

Abstract: A new borate, PbTeB4O9, with unprecedented 2D infinite [TeB4O9]∞ layers was obtained; it possesses a calculated birefringence of 0.099 at 1064 nm.

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A Noncentrosymmetric Metal‐Free Borophosphate: Achieving a Large Birefringence and Excellent Stability by Covalent‐Linkage

Zhang,

Jiao,

et al. 2024

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Organic–inorganic hybrid linear and nonlinear optical (NLO) materials have received increasingly wide spread attention in recent years. Herein, the first hybrid noncentrosymmetric (NCS) borophosphate, (C5H6N)2B2O(HPO4)2 (4PBP), is rationally designed and synthesized by a covalent‐linkage strategy. 4‐pyridyl‐boronic acid (4 PB) is considered as a bifunctional unit, which may effectively improve the optical properties and stability of the resultant material. On the one hand, 4 PB units are covalently linked with PO3(OH) groups via strong B–O–P connections, which significantly enhances the thermal stability of 4PBP (decomposition at 321, vs lower 200 °C of most of hybrid materials). On the other hand, the planar π‐conjugated C5H6N units and their uniform layered arrangements represent large structural anisotropy and hyperpolarizability, achieving the largest birefringence (0.156 @ 546 nm) in the reported borophosphates and a second‐harmonic generation response (0.7 × KDP). 4PBP also exhibits a wide transparency range (0.27–1.50 µm). This work not only provides a promising birefringent material, but also offers a practical covalent‐attachment strategy for the rational design of new high‐performance optical materials.

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A Noncentrosymmetric Metal‐Free Borophosphate: Achieving a Large Birefringence and Excellent Stability by Covalent‐Linkage

Zhang,

Jiao,

et al. 2024

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Investigations of structure, thermal stability and optical properties of a new NLO crystal (C3H5N2)+(CF3COO)-

Meng,

Liu,

et al. 2025

Journal of Molecular Structure

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The synthesis, structures and characterizations of (C5H12NO)4Cd3Cl10·2H2O and (C5H12NO)2BiCl6·H5O2 crystals

Shen,

liu,

Wang

et al. 2025

Journal of Molecular Structure

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PbTeB₄O₉: a lead tellurium borate with unprecedented fundamental building block [B₄O₁₀] and large birefringence

Abstract: A new borate, PbTeB4O9, with unprecedented 2D infinite [TeB4O9]∞ layers was obtained; it possesses a calculated birefringence of 0.099 at 1064 nm.

Cited by 3 publications

References 67 publications

A Noncentrosymmetric Metal‐Free Borophosphate: Achieving a Large Birefringence and Excellent Stability by Covalent‐Linkage

A Noncentrosymmetric Metal‐Free Borophosphate: Achieving a Large Birefringence and Excellent Stability by Covalent‐Linkage

Investigations of structure, thermal stability and optical properties of a new NLO crystal (C3H5N2)+(CF3COO)-

The synthesis, structures and characterizations of (C5H12NO)4Cd3Cl10·2H2O and (C5H12NO)2BiCl6·H5O2 crystals

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