In recent years, accurate estimation and spatial mapping of above-ground carbon (AGC) storage in forests have been crucial for formulating carbon trading policies and promoting sustainable development strategies. Forest structure complexities mean that during their growth, trees may be affected by the surrounding environment, giving rise to spatial autocorrelation and heterogeneity in nearby forest segments. When estimating forest AGC through remote sensing, data saturation can arise in dense forest stands, adding to the uncertainties in AGC estimation. Our study used field-measured stand factors data from 138 forest fire risk plots located in Fenglin County in the Northeastern region, set within a series of temperate forest environments in 2021 and Sentinel-2 remote sensing image data with a spatial resolution of 10 m. Using ordinary least squares (OLS) as a baseline, we constructed and compared it against four spatial regression models, spatial lag model (SLM), spatial error model (SEM), spatial Durbin model (SDM), and geographically weighted regression (GWR), to better understand forest AGC spatial distribution. The results of local spatial analysis reveal significant spatial effects among plot data. The GWR model outperformed others with an R2 value of 0.695 and the lowest rRMSE at 0.273, considering spatial heterogeneity and extending the threshold range for AGC estimation. To address the challenge of light saturation during AGC estimation, we deployed traditional linear functions, the generalized additive model (GAM), and the quantile generalized additive model (QGAM). AGC light saturation values derived from QGAM most accurately reflect the actual conditions, with the forests in Fenglin County exhibiting a light saturation range of 108.832 to 129.894 Mg/ha. The GWR effectively alleviated the impact of data saturation, thereby reducing the uncertainty of AGC spatial distribution in Fenglin County. Overall, accurate predictions of large-scale forest carbon storage provide valuable guidance for forest management, forest conservation, and the promotion of sustainable development strategies.