Over the past few years our group has described a new type of alkene difunctionalization reaction in which aryl or alkenyl triflates bearing tethered alkenes are coupled with various nucleophiles to afford carbocyclic products. The products are formed in moderate to good chemical yield, with generally high levels of stereoselectivity. Our progress to date in this area, which includes reactions of amine, alcohol, enolate, and indole nucleophiles, is described in this review. Scheme 4. Optimization of the Enantioselective Reaction Scheme 5. Enantioselective alkene carboamination reactions Scheme 6. Carboamination reactions of cyclic alkenyl triflates Review Isr. J. Chem. 2020, 60, 259 -267 66 % yield, reproducible Scheme 13. Reactions of indole nucleophiles