Handbook of CH-Functionalization 2022
DOI: 10.1002/9783527834242.chf0006
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Pd‐Catalyzed C(sp 3 )H Activation by Native Directing Groups

Abstract: In this article, we discuss the recent developments in palladium (Pd)‐catalyzed C(sp 3 )H activation assisted by native directing groups. Although studies on preinstalled (exogenous) directing group‐aided Pd‐catalyzed C(sp 3 )H functionalization reactions are still emerging, research on Pd‐catalyzed C(sp 3 )H activation assisted by native directing groups is growing at a considerable pace. Native directing groups refer to inherent funct… Show more

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Cited by 4 publications
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“…Subsequently, we intended to explore the native carboxylic acid group aided C–H arylation 2p q of carbazole-3-carboxylic acid 4a (Table 2 ). Towards this end, we performed the β-C–H arylation of N -ethylcarbazole-3-carboxylic acid ( 4a ) with 6a in the presence of Pd(OAc) 2 as catalyst (6–10 mol%) and NMe 4 Cl and KOAc as additives in AcOH or TFA at 120 °C for 24 hours.…”
Section: Table 1 Screening Of Reaction Conditions For T...mentioning
confidence: 99%
“…Subsequently, we intended to explore the native carboxylic acid group aided C–H arylation 2p q of carbazole-3-carboxylic acid 4a (Table 2 ). Towards this end, we performed the β-C–H arylation of N -ethylcarbazole-3-carboxylic acid ( 4a ) with 6a in the presence of Pd(OAc) 2 as catalyst (6–10 mol%) and NMe 4 Cl and KOAc as additives in AcOH or TFA at 120 °C for 24 hours.…”
Section: Table 1 Screening Of Reaction Conditions For T...mentioning
confidence: 99%