Cobalt-Chrome nanoparticles-incorporated carbon nano¯bers (CNFs) are proposed as an e®ec-tive nonprecious electrocatalyst for methanol oxidation in the alkaline media. The introduced nano¯bers were prepared by simple technique, electrospinning. Carbonization of as-spun mat composed of chromium acetate, cobalt acetate and poly(vinyl alcohol) (PVA) at high temperature (900 C) leads to production of the introduced nano¯bers. The physicochemical characteristics were investigated by X-ray di®ractometer (XRD), scanning electron microscope (SEM), eld emission scanning electron microscope (FESEM), transmission electron microscope (TEM) equipped with EDX and TEM mapping. The exploited analyses con¯rmed that the¯nal product is in the form of CNFs decorated by Co/Cr nanoparticles. Based on the results obtained from the cyclic voltammetry (CV) measurements, the proposed Co/Cr-incorporated CNFs possess high electrocatalytic activity toward methanol electrooxidation as a clear peak of methanol oxidation appeared with corresponding current density of 56 mA/cm 2 . Moreover, the current density increased by increasing methanol concentration up to 4.0 M. Overall, the proposed nano¯bers open new avenue for platinum-free and stable nanostructural catalysts for fuel cell technology.