With Pb-free solder joints containing SnAg -Cu-based ternary alloys (Sn-1.0 wt.%Ag-0.5Cu and Sn-4.0Ag-0.5Cu) and SnAg -Cu-In-based quaternary alloys (Sn-1.0Ag-0.5Cu-1.0In, Sn-1.2Ag-0.5Cu-0.4In, Sn-1.2Ag-0.5Cu-0.6In, and Sn-1.2Ag-0.7Cu-0.4In), fracture-mode change, shear strengths, and fracture energies were observed and measured under a high-speed shear test of 500 mm/s. The samples in each composition were prepared with as-reflowed ones or solid-aged ones at 125 o C to 500 h. As a result, it was observed that ductile or quasi-ductile fracture modes occurs in the most of SnAg -Cu-In samples. The happening frequency of a quasi-ductile fracture mode showed that the SnAg -Cu-In joints possessed ductile fracture properties more than that of Sn-3.0Ag-0.5Cu in the high-speed shear condition. Moreover, the SnAg -Cu-In joints presented averagely fracture energies similar to those of SnAg -Cu joints. While maximum values in the fracture energies were measured after the solid aging for 100 h, clear decreases in the fracture energies were observed after the solid aging for 500 h. This result indicated that reliability degradation of the SnAg -Cu-In solder joints might accelerate from about that time.