ChemistrySelect
 2023
DOI: 10.1002/slct.202303124
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Pd(II)‐Catalyzed β‐C(sp3)−H Functionalization of Ugi 4‐CR Adducts Using the 2‐(Methylthio)‐aniline (MTA) Directing Group

Silvia J. Becerra‐Anaya,
Luis A. Polindara‐García

Abstract: The multicomponent assembly of the 2‐(methylthio)‐aniline (MTA) directing group in N‐methylated Ugi 4‐CR adducts using the (2‐isocyanophenyl)(methyl)sulfane and the subsequent Pd(II)‐mediated mono‐selective β‐C(sp3)−H bond activation process have been successfully developed for the synthesis of arylated amino acids and peptide systems.

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Mechanochemical Assembly of a Nitrile‐Based Directing Group in Arylacetic Acids Using the Passerini 3‐CR: Exploration of the Pd(II)‐Catalyzed meta‐C(sp2)−H Bond Olefination Process

García‐Uribe,
Martínez‐Flores,
Martínez‐Barrita
et al. 2024
Eur J Org Chem
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Mechanochemical Assembly of a Nitrile‐Based Directing Group in Arylacetic Acids Using the Passerini 3‐CR: Exploration of the Pd(II)‐Catalyzed meta‐C(sp2)−H Bond Olefination Process

García‐Uribe,
Martínez‐Flores,
Martínez‐Barrita
et al. 2024
Eur J Org Chem
Self Cite
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