PdZn on ZSM-5 nanoparticles for CO2 hydrogenation to dimethyl ether: comparative in situ analysis with Pd/TiO2 and PdZn/TiO2

CO2 to dimethyl ether (DME): structural and functional insights of hybrid catalysts

“…8). 88 They found that CO 2 was converted to adsorbed carbonate and subsequently hydrogenated to bicarbonate and methoxy CH 3 O* over Pd and PdZn species. However, the presence of Pd promotes C–O dissociation to form methane, while PdZn improves methanol formation through the stabilization of methoxy on TiO 2 .…”

The lattice oxygen determines the methanol selectivity in CO2 hydrogenation over ZnZrOx catalysts

“…1 In this context, the implementation of carbon-neutral policies has gained widespread consensus in the international community, encouraging researchers to pay more attention to research on the highly efficient chemical utilization of CO 2 . 2 CO 2 can be converted into methanol, [3][4][5][6] ethanol, 7,8 higher alcohols, 9 aromatics, 10 gasoline grade hydrocarbons, 11 dimethyl ether, 12 and olefins. 13 The hydrogenation of CO 2 to methanol has attracted increasing interest for carbon capture, utilization, and storage.…”