“…These natural sources of metals, along with the anthropogenic enrichment from mining operations (Alsina et al, ; Bugueno, Acevedo, Bonilla, Pizarro, & Pasten, ; Leiva et al, ; Oyarzun & Oyarzun, ; Oyarzun et al, ) affect both water and sediment quality within the region. It is well known that the origin and effects of acid mine drainage and acid rock drainage are largely controlled by hydrological processes (Cravotta, Goode, Bartles, Risser, & Galeone, ; Harpold, Burns, Walter, Shaw, & Steenhuis, ; Johnson & Thornton, ; Kimball, Broshears, Bencala, & McKnight, ; McKnight et al, ; Papassiopi et al, ; Pellegrini, Garcia, Penas‐Castejon, Vignozzi, & Costantini, ; Wan, Liu, Munroe, & Cai, ). A systematic increase in the concentration of arsenic, copper, iron, and sulfate in Andean watersheds (Pizarro, Vergara, Rodriguez, & Valenzuela, ; Pizarro, Vergara, Morales, Rodriguez, & Vila, ) highlights the need to further improve conceptual models and expand datasets describing the processes underlying the behavior of dissolved and particle‐bound metal fluxes.…”