PEDOT-PSS based 2-in-1 step-by-step films: A refined study

Saint-Aubin, Christine de; Hassan, Mohammad El Hajj; Kunemann, Philippe; Patois, Tilia; Lakard, Boris; Fabre, Roxane; Hemmerlé, Joseph; Schaaf, Pierre; Nardin, M.; Vallat, Marie‐France

doi:10.1016/j.synthmet.2014.04.003

Cited by 6 publications

(3 citation statements)

References 27 publications

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“…This dopant has been used to modify the PEDOT: PSS film. Dbbelin [11] et al used 1-butyl-3-methylimidazolium tetrafluoroborate (bmim: BF4) as an additive (1.5 wt% in solution) to increase the conductivity of PEDOT: PSS to 130 S/cm. The IL expanded the polystyrene chains and induced a favorable phase separation with a size of approximately 40-60 nm.…”

Section: Introductionmentioning

confidence: 99%

“…The IL expanded the polystyrene chains and induced a favorable phase separation with a size of approximately 40-60 nm. Badre [11] et al demonstrated the high conductivity of PEDOT: PSS films by doping 1-ethyl-3-methylimidazole tetracyanoborates (EMIM: TCB, 1.57 wt% solution) into aqueous PEDOT: PSS solution. After the addition of EMIM: Trichlorobenzene to the cathode protective film, the conductivity significantly increased to 2084 S/cm.…”

Section: Introductionmentioning

confidence: 99%

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Preparation and Properties of PEDOT:PSS-Based Thermoelectric Thin Films

Jin

Zhang

2022

MSF

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PEDOT:PSS (poly (3,4-ethylenedioxythiophene)-poly (styrenesulfonate)) has the advantages of excellent thermoelectric properties, good environmental stability, outstanding processability, etc. It is a new type of polymer thermoelectric material with great development potential to improve its conductivity and Seebeck coefficient by compounding or doping with nanomaterials. In this study, PEDOT:PSS was composited with carbon nanotubes (CNTs) to prepare PEDOT:PSS/CNT composite films with excellent thermoelectric properties. The ionic liquid (IL) and polymer surfactants (PEG, PEG-PPG-PEG) doping on the thermoelectric properties of the composite system. The maximum electrical conductivity and Seebeck coefficient of the prepared PEDOT:PSS/CNT composite film are 1581.06 S/cm (CNT content of 10 wt%) and 20.28 μV/K (CNT content of 40 wt%), respectively, and the maximum power factor can reach 52.51 μW ·m-1·K-2 (CNT content is 30wt%). After the introduction of PEG doping, the Seebeck coefficient can reach up to 23.62 μV/K.

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Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Preparation and Properties of PEDOT:PSS-Based Thermoelectric Thin Films

Jin

Zhang

2022

MSF

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“…5,8,9,12,13,[19][20][21] Hesse 7 also states that conventional four point probe measurement methods are unsuitable if Schottky behavior occurs between the metallic contact and the sample.…”

Section: Introductionmentioning

confidence: 99%

The role of probe oxide in local surface conductivity measurements

Barnett

Kryvchenkova

Wilson

et al. 2015

Journal of Applied Physics

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A four-point surface conductivity probe suitable for in situ ultrahigh vacuum conductivity measurements Rev.Local probe methods can be used to measure nanoscale surface conductivity, but some techniques including nanoscale four point probe rely on at least two of the probes forming the same low resistivity non-rectifying contact to the sample. Here, the role of probe shank oxide has been examined by carrying out contact and non-contact I V measurements on GaAs when the probe oxide has been controllably reduced, both experimentally and in simulation. In contact, the barrier height is pinned but the barrier shape changes with probe shank oxide dimensions. In non-contact measurements, the oxide modifies the electrostatic interaction inducing a quantum dot that alters the tunneling behavior. For both, the contact resistance change is dependent on polarity, which violates the assumption required for four point probe to remove probe contact resistance from the measured conductivity. This has implications for all nanoscale surface probe measurements and macroscopic four point probe, both in air and vacuum, where the role of probe oxide contamination is not well understood. V C 2015 AIP Publishing LLC. [http://dx.

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