This article explores the electromechanical performance of poly(vinylidene fluoride) (PVDF) films with silver nanoplatelets on smooth polydimethylsiloxane (PDMS) substrates. PVDF, a semi‐crystalline polymer, shows piezoelectric properties when processed at low temperatures, making it ideal for energy harvesting and sensors. This research addresses a gap by examining high strain rate and complex electromechanical characteristions of PVDF composites, which are underexplored. Films, fabricated using a non‐vacuum rod coating method, underwent dynamic electromechanical tests (strain rate ~ 2 s−1), including stretching, twisting, combined stretching and twisting, and forced vibrations. Results show the films function up to 17% applied strain with a gage factor of 10.57. In twisting tests, the laminates perform up to 387° in slow twisting (gage factor = 28.34) and 341° in fast twisting (gage factor = 7.65). Combined stretching and twisting tests show performance decreases, with functionality up to 6.24% strain at a twist angle of 330.1°. Vibration tests reveal that increased amplitude reduces performance, with the laminates enduring frequencies between 4.35 and 12.14 Hz. The films also exhibit a linear piezoelectric response, with a maximum open circuit voltage of 37.2 V under an impact load of 1112 N, underscoring the potential of PVDF/Ag nanocomposites for advanced MEMS applications.