In this article, we explore the possibilities of studying transport phenomena that involve non-aqueous phase liquids (NAPL) by means of magnetic resonance imaging (MRI) with a paramagnetic contrast agent. We studied n-octanol as a model NAPL, especially in alcohol flooding in a water-saturated sediment, and flood-drainage-cycles in a temporally unsaturated sediment column. While the 'natural' relaxation time contrast between water and n-octanol often allows a distinction of the two liquids in a quartz-sand sediment, the use of Mn 2þ -ions dissolved in the water phase as a 'biphasic' contrast agent allows much better discrimination between the different liquid phases and also considerably faster imaging. Using a 3D FLASH sequence, a NAPL-saturated region can be visualized against a background of water-saturated sediment in 11 s with a resolution of 1.9 Â 1.9 Â 3.2 mm 3 .