Selective solar absorbers play a pivotal role in harnessing renewable energy
sources and offer considerable potential for efficient photothermal
conversion. However, most highly efficient solar selective absorbers
require complex structural designs or combinations of multiple
materials to implement. Here, we design a spectrum selective solar
absorber using only chromium, featuring a cross-shaped square cavity
structure. The absorber exhibits a total solar absorption of 96.2%
while maintaining a total emissivity of 12%. The distributions of
electric field indicate that the outstanding spectrum absorption is
caused by the synergistic interplay between surface plasmon resonance,
cavity resonance, and guided mode resonance. Our study delves into how
different geometric parameters influence the spectrum absorption of
the absorber. Additionally, we investigate the performance of the
selective solar absorber in terms of absorption at various angles of
incidence. Remarkably, even at a substantial angle of 60°, it sustains
a high absorption of approximately 80%. At 100°C, the absorber
achieves an 86% photothermal conversion efficiency. Furthermore, as
the concentration factor increases, the impact of high temperature on
the absorber’s photothermal conversion efficiency diminishes. When the
concentration factor is 200, the absorber achieves a steady-state
temperature exceeding 753°C. This work holds importance in
photothermal conversion and thermophotovoltaics.