A numerical simulation has been carried out in this study to evaluate the effect of alcohol addition to the blends of diesel and palm stearin biodiesel on the performance, combustion and emission of a diesel engine. The commercial software Diesel-RK has been used in this study to simulate a single-cylinder, naturally aspirated, direct injection, four-stroke diesel engine. The simulated results have been validated against experimental observation for the base fuel diesel. The effects of two alcohols, namely ethanol and methanol have been separately investigated and compared. The results indicate that although the brakespecific fuel consumption is slightly increased, the other performance characteristics and the entire combustion and emission parameters are improved with alcohol addition to diesel-biodiesel blends. The instantaneous heat release rate, ignition delay and oxides of nitrogen emission are found to be more with methanol than with ethanol. The diesel-biodiesel blend also shows better combustion and emission characteristics than that of diesel except oxides of nitrogen emission. Abbreviation CI Compression ignition CO 2 Carbon dioxide NO x Oxides of nitrogen PM Particulate matter BE20 A blend of 20 % ethanol and 80 % methyl soyate (by volume) HC Hydrocarbon THC Total hydrocarbon CO Carbon monoxide LHV Lower heating value SO x Oxides of sulphur bTDC Before top dead centre PSME Palm stearin methyl ester DP15 A blend of 15 % palm stearin methyl ester and 85 % diesel DPSE15 A blend of 15 % palm stearin methyl ester, 15 % ethanol and 70 % diesel DPSM15 A blend of 15 % palm stearin methyl ester, 15 % methanol and 70 % diesel List of symbols _ m j Mass flow rate of the jth species (kg/sec) m The total mass within the control cylinder (kg) m i Mass of the ith species (kg/sec) Y j i Stoichiometric coefficients on the product side Y cyl i Stoichiometric coefficients on the reactant side _ S gen Net generation rate of the ith species (kg/sec) X i Molar Rate of Production (mol/sec) W mw Molecular weight (kg/mol) v Specific volume (m 3 /kg) q Density (kg/m 3 ) _ m a Air mass flow rate into the engine (kg/sec) _ m f Fuel mass flow rate into the engine (kg/sec) x Angular crank velocity (rpm) m a Engine intake air flow rate (kg/sec) s Time (sec) n Engine speed (rpm)