The forthcoming wireless networks must integrate to a high density of end‐user devices while ensuring a superior quality of service. It is imperative to devise solutions that reduce the density of wireless access points and associated costs, while simultaneously ensuring security and privacy throughout propagation. Herein, a novel dual‐band photodetector with high selective responsivities in distinct visible and near‐infrared (NIR) band is developed as an optical signal receiver. The receiver has an unprecedented fast switch speed > 500 kHz between different operation modes. Leveraging this fast switch speed, a high‐speed Multiple‐Input‐Single‐Output (MISO) system is developed, fusing spectrum resources from visible to infrared bands. The system achieves a data rate of 600 Kbps in the visible channel and 500 Kbps in the NIR channel, with a sum rate of 1.1 Mbps. This is the highest single‐channel data rate and sum rate among reported dual‐band photodetectors. Additionally, two previously overlooked mechanisms, the Subtraction and Addition modes, are studied in detail. The four operation modes are developed to establish a novel physical encryption method in terms of arithmetic relation. The dual‐channel coupled link can support a data rate of 200 Kbps, significantly enhancing communication security.