Performance enhancement of perovskite solar cells by doping non-toxic multifunctional natural sodium lignosulfonate into SnO<sub>2</sub>

Jiang, Zezhuan; Li, Fuling; Yan, Huaiqing; R, Rathes Kannan; Chen, Lijia; Li, Ping; Song, Qunliang

doi:10.1039/d3gc04924h

Green Chem.

2024

DOI: 10.1039/d3gc04924h

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Performance enhancement of perovskite solar cells by doping non-toxic multifunctional natural sodium lignosulfonate into SnO₂

Zezhuan Jiang,

Fuling Li,

Huaiqing Yan

et al.

Abstract: The buried interface between perovskite and the electron transport layer (ETL) plays a crucial role in improving the power conversion efficiency (PCE) and stability of n-i-p structured perovskite solar cells...

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Cited by 2 publications

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Recent Progress on Cross‐Linkable Fullerene‐Based Electron Transport Materials for Perovskite Solar Cells

Zhou,

Luo,

Wang

et al. 2024

ChemSusChem

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Fullerene‐based derivatives are frequently used as electron transport materials (ETMs) and interface buffers for perovskite solar cells (PSCs) due to their excellent properties, including high electron affinity and mobility, low recombination energy, tunable energy levels, and solution processability. However, significant challenges arise because fullerene derivatives tend to aggregate and dimerize, which reduces exciton dissociation and charge transport capacity. Additionally, their chemical compatibility with perovskite absorbers facilitates halide diffusion and degradation of PSCs. This overlap causes delamination and dissolution during device fabrication, hindering the performance enhancement of fullerene‐based PSCs. To address these issues, researchers have developed cross‐linkable fullerene materials. These materials have been shown to not only significantly improve the power conversion efficiency (PCE) of PSCs but also effectively enhance the device stability. In this review, we summarized recent research progress on cross‐linkable fullerene derivatives as ETMs for PSCs. We systematically analyze the impact of these cross‐linked ETMs on device performance and long‐term stability, focusing on their molecular structures and working mechanisms. Finally, we discuss the future challenges that need to be overcome to advance the application of cross‐linkable fullerene materials in PSCs.

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Recent Progress on Cross‐Linkable Fullerene‐Based Electron Transport Materials for Perovskite Solar Cells

Zhou,

Luo,

Wang

et al. 2024

ChemSusChem

View full text Add to dashboard Cite

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Natural molecule Niacin enables printable carbon-based mesoscopic perovskite solar cells with 17.3% efficiency

Tao,

Chen,

Shao

et al. 2024

J Mater Sci: Mater Electron

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Performance enhancement of perovskite solar cells by doping non-toxic multifunctional natural sodium lignosulfonate into SnO₂

Abstract: The buried interface between perovskite and the electron transport layer (ETL) plays a crucial role in improving the power conversion efficiency (PCE) and stability of n-i-p structured perovskite solar cells...

Cited by 2 publications

References 61 publications

Recent Progress on Cross‐Linkable Fullerene‐Based Electron Transport Materials for Perovskite Solar Cells

Recent Progress on Cross‐Linkable Fullerene‐Based Electron Transport Materials for Perovskite Solar Cells

Natural molecule Niacin enables printable carbon-based mesoscopic perovskite solar cells with 17.3% efficiency

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Performance enhancement of perovskite solar cells by doping non-toxic multifunctional natural sodium lignosulfonate into SnO2

Abstract: The buried interface between perovskite and the electron transport layer (ETL) plays a crucial role in improving the power conversion efficiency (PCE) and stability of n-i-p structured perovskite solar cells...

Cited by 2 publications

References 61 publications

Recent Progress on Cross‐Linkable Fullerene‐Based Electron Transport Materials for Perovskite Solar Cells

Recent Progress on Cross‐Linkable Fullerene‐Based Electron Transport Materials for Perovskite Solar Cells

Natural molecule Niacin enables printable carbon-based mesoscopic perovskite solar cells with 17.3% efficiency

Contact Info

Product

Resources

About

Performance enhancement of perovskite solar cells by doping non-toxic multifunctional natural sodium lignosulfonate into SnO₂