Renewable energy sources, such as solar energy, could potentially provide an affordable alternative to conventionally generated electricity, especially in locations like the Caribbean which tend to have an abundant solar resource, but also high cost for electricity. Thin film and hybrid solar devices, including Dye-Sensitized Solar Cells (DSSCs), are especially promising energy solutions, due to the low cost of materials and equipment required for their fabrication. In this paper, we investigate the effect of doping titanium dioxide based DSSC photoanodes with lanthanum, cerium, and praseodymium species on the overall performance of the cell, along with results from optimization of the best performing cell formulation according to sintering time and sintering temperature, giving a maximum 39% increase in device efficiency.