Performance of carbon-fiber-containing LiFePO4 cathodes for high-power applications

Thorat, Indrajeet V.; Mathur, Vipul; Harb, John N.; Wheeler, Dean R.

doi:10.1016/j.jpowsour.2006.06.032

Cited by 83 publications

(45 citation statements)

References 19 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The former were found to have better power performance. Thorat thought the combination of CF and CB provided a highly conductive network that connected well to the active material particles and the current collector [18]. Similar works were also done by Zhang, using BCA containing CNT and AB [19].…”

Section: Introductionsupporting

confidence: 54%

Role of mesopores on the electrochemical performance of LiCoO2 composite cathodes for lithium ion batteries

Zhang

Fan

Wang

et al. 2011

Ionics

View full text Add to dashboard Cite

Mesoporous carbon (MC) was utilized to increase the mesoporosity of LiCoO 2 composite cathode. Graphite powder (GP) was chosen as a standard of comparison because of its very low mesoporosity. Compared with MC, GP has similar particle size, lower specific surface area, and higher electronic conductivity. Acetylene black (AB) exists in the form of chains of nanoparticles. With all other factors held constant, the mixture of AB and MC (ABMC)-loaded LiCoO 2 composite cathode (ABMC cathode) was superior to the mixture of AB and GP (ABGP)-loaded LiCoO 2 composite cathode (ABGP cathode). The reason is described as follows. Both GP and MC form a conductive network with AB chains. ABGP cathode has higher electronic conductivity than ABMC cathode. But the ionic conductivity of the ABMC cathode is more easily enhanced than the ABGP cathode because the former has much greater mesoporosity. In addition, the mesopores absorb and retain electrolyte solution and then provide buffer lithium ions for quick electrochemical reactions, so shortening the lithium ion transfer path in the composite cathode.

show abstract

Section: Introductionsupporting

confidence: 54%

Role of mesopores on the electrochemical performance of LiCoO2 composite cathodes for lithium ion batteries

Zhang

Fan

Wang

et al. 2011

Ionics

View full text Add to dashboard Cite

show abstract

“…In comparison with LiFePO 4 , which is now successfully optimized for high-power applications [1,2], the operating voltage of LiMnPO 4 is higher, but the rate capability is significantly lower [3]. The key ratelimiting factor was suggested to be the high effective mass of polarons, resulting from Jahn-Teller anisotropic lattice deformation around an Mn 3+ -ion [3].…”

Section: Introductionmentioning

confidence: 99%

Precursor-based synthesis and electrochemical performance of LiMnPO4

Bramnik

Ehrenberg

2008

Journal of Alloys and Compounds

View full text Add to dashboard Cite

“…However, the major drawback with LiFePO 4 is the poor lithium ions conductivity and the low intrinsic electronic conductivity, which have limited its power-demanding applications such as hybrid electric vehicles [3][4][5][6][7]. A great deal of effort has been made in the past decade to solve the conductivity problem.…”

Section: Introductionmentioning

confidence: 99%

Synthesis of LiFePO4/carbon composite from nano-FePO4 by a novel stearic acid assisted rheological phase method

Huang

Ren

Peng

et al. 2009

Electrochimica Acta

View full text Add to dashboard Cite

Performance of carbon-fiber-containing LiFePO4 cathodes for high-power applications

Cited by 83 publications

References 19 publications

Role of mesopores on the electrochemical performance of LiCoO2 composite cathodes for lithium ion batteries

Role of mesopores on the electrochemical performance of LiCoO2 composite cathodes for lithium ion batteries

Precursor-based synthesis and electrochemical performance of LiMnPO4

Synthesis of LiFePO4/carbon composite from nano-FePO4 by a novel stearic acid assisted rheological phase method

Contact Info

Product

Resources

About