2019
DOI: 10.1039/c8fd00162f
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Performance of enhanced DuBois type water reduction catalysts (WRC) in artificial photosynthesis – effects of various proton relays during catalysis

Abstract: A pincer type ligand provides an additional coordination site or a proton relay depending on the metal oxidation state.

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Cited by 11 publications
(55 citation statements)
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“…While some metal complexes of ligand 1 have been published, now we present the single crystal structure of the uncomplexed PNP Me ligand for the first time ( Figure 1). [14] Selected bond lengths and angles are given in Table 1. The P-CH 2 bond lengths of 1.8678(17) and 1.8680 (16) Å, respectively, are elongated compared with the mean value of 1.8363 Å for the P-anisyl bond lenghts reflecting the aryl effect in the latter case.…”
Section: Solid State Structuresmentioning
confidence: 99%
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“…While some metal complexes of ligand 1 have been published, now we present the single crystal structure of the uncomplexed PNP Me ligand for the first time ( Figure 1). [14] Selected bond lengths and angles are given in Table 1. The P-CH 2 bond lengths of 1.8678(17) and 1.8680 (16) Å, respectively, are elongated compared with the mean value of 1.8363 Å for the P-anisyl bond lenghts reflecting the aryl effect in the latter case.…”
Section: Solid State Structuresmentioning
confidence: 99%
“…This could lead to subtle differences in photocatalytic activity, which have been observed earlier. [14] The crystal structure of [PtCl 2 (PNP Me )] (15) is shown in Figure 5 and selected bond lengths and angles are given in Table 3. The Pt-P bond lengths of 2.2215(11) and 2.2260(10) Å, respectively, are identical within statistical significance.…”
Section: Solid State Structuresmentioning
confidence: 99%
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“…In the 3 rd Faraday Discussion on Artificial Photosynthesis in Cambridge, UK, different possible approaches to develop a functional and commercially viable solar-to-chemical energy conversion device were covered ( Figure 1). These approaches are based on different classifications of Artificial Photosynthesis research, which depend on the nature of the materials used (Section 2.1), [32][33][34][35][36][37][38][39][40][41][42][43][44][45] the degree of system integration (Section 2.2), [46][47][48][49] and the substrates and products involved (Section 2.3). [50][51][52][53] In this article, we will firstly discuss the main motivations for Artificial Photosynthesis research.…”
Section: Introductionmentioning
confidence: 99%