Conductive polymer composite-based strain sensors are
essential
components of flexible wearable devices. However, nonmonotonic responses
with shoulder peaks limit their practical application. Herein, we
innovatively optimized the shoulder-peak phenomenon in a strain-sensing
composite nanofiber filament by regulating carbon nanomaterial dispersion.
Further, the preparation methods, characteristics, and performances
of the filament strain sensors were systematically introduced. On
this basis, transmission electron microscopy, finite element analysis,
and mathematic and structural evolution models were used to explore
the origin of shoulder peaks and explain the sensing mechanism of
conductive networks. Results confirmed that the beacon tower-shaped
conductive network designed by constructing nanofiller agglomerates
could cause strain concentration and resist the Poisson transverse
contraction of nanofibers, considerably improving the monotonicity
and sensitivity of the sensor. The strain-sensing performance was
optimal when the nanofillers were dispersed using 2.5 wt % of an anionic
dispersant. The sensor exhibited a maximum detective strain of 120%,
an ultralow detection limit of 0.01%, and high sensitivity and linearity
of 9.66 and 0.996 within 20% strain, respectively. Moreover, it showed
the advantages of a fast response time (120 ms), excellent durability
(3000 cycles), anti-interference, washability, and antibacterial capability.
Finally, a smart Kinesio tape was developed for protecting/treating
the human body and detecting joint/muscle movement via simple sewing.