Performance of metal-functionalized rice husk cellulose for CO2 sorption and CO2/N2 separation

Campbell, Sarah; Bernard, Franciele L.; Rodrigues, Daniela M.; Carreño, Luz Ángela; Chaban, Vitaly V.; Einloft, Sandra

doi:10.1016/j.fuel.2018.11.078

Cited by 24 publications

(5 citation statements)

References 81 publications

(116 reference statements)

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“…In our previous work we reported the bonding of the metal oxide (Fe 2 O 3 and TiO 2 ) on the cellulose surface via hydroxyl group. The metal modified cellulose showed a significant enhancement in the CO 2 sorption uptake compared to non-modified cellulose [57]. Based on our previous experience and the results of the present work one can conclude that the presence of the metals oxides and their proper dispersion in the ionic liquid and polymer matrix can improve significantly CO 2 sorption capacity.…”

Section: Solubility Measurementsupporting

confidence: 67%

New polysulfone microcapsules containing metal oxides and ([BMIM][NTf2]) ionic liquid for CO2 capture

Nisar

Bernard

Duarte

et al. 2021

Journal of Environmental Chemical Engineering

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Section: Solubility Measurementsupporting

confidence: 67%

New polysulfone microcapsules containing metal oxides and ([BMIM][NTf2]) ionic liquid for CO2 capture

Nisar

Bernard

Duarte

et al. 2021

Journal of Environmental Chemical Engineering

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“…This behavior is related to sample S specific surface area being twice as large as sample A (Table 2). Unlike CO 2 sorption, selectivity (CO 2 /N 2 ) of sample A is higher when compared to sample S. This behavior is attributed to metal presence in sample A improving support/CO 2 affinity 1,58,59,62,63 . Comparing CO 2 sorption capacity of IL immobilized samples one can observe a reduction in CO 2 sorption values for all samples.…”

Section: Influence Of Anion On Co 2 Sorption Capacitymentioning

confidence: 91%

Imidazolium-based Ionic Liquids Impregnated in Silica and Alumina Supports for CO2 Capture

et al. 2019

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Ionic liquids (ILs) physical immobilization in solid materials is a key strategy for developing efficient and low cost CO 2 capture processes. In this work, two porous commercial substrates with different characteristics (silica and alumina) were impregnated with ILs by physical wet method. Imidazolium based IL combined with [Br]and [Tf 2 N]anions were used in impregnation process. CO 2 sorption capacity and selectivity (CO 2 /N 2) of these materials were investigated. The best results regarding CO 2 /N 2 selectivity and CO 2 sorption were obtained with [Tf 2 N]anion. In relation to solid support, commercial alumina exhibited enhanced CO 2 uptake and higher selective capacity (CO 2 /N 2) (6.1 (± 0.1)). Combination of commercial alumina as support and 20 wt% of mbmim [Tf 2 N] resulted in higher CO 2 /N 2 selectivity of 9.5 ± 1.0. In addition, this material also showed fast sorption kinetics when compared to pure IL besides reuse capacity.

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“…The samples were degassed overnight (250 °C, ∼0.2 mbar) and further degassed in situ for 6 h (0.003 mbar) before the analysis. This degassing temperature was selected to align with operational temperatures of the CDRA onboard the ISS, as well as to follow previous reports − . The surface areas of the samples were calculated using the Brunauer–Emmett–Teller (BET) method, and the total pore volume was calculated from the volume of N 2 adsorbed at P / P 0 = 0.99.…”

Section: Methodsmentioning

confidence: 99%

Intrinsic Thermal Desorption in a 3D Printed Multifunctional Composite CO₂ Sorbent with Embedded Heating Capability

Thompson

Bellerjeau

Marinick

et al. 2019

ACS Appl. Mater. Interfaces

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Efficient removal of CO2 from enclosed environments is a significant challenge, particularly in human space flight where strict restrictions on mass and volume are present. To address this issue, this study describes the use of a multimaterial, layer-by-layer, additive manufacturing technique to directly print a structured multifunctional composite for CO2 sorption with embedded, intrinsic, heating capability to facilitate thermal desorption, removing the need for an external heat source from the system. This multifunctional composite is coprinted from an ink formulation based on zeolite 13X, and an electrically conductive sorbent ink formulation, which includes metal particles blended with the zeolite. The composites are characterized using analytical and imaging tools and then tested for CO2 adsorption/desorption. The resistivity of the conductive sorbent is <2 mΩ m, providing a temperature increase up to 200 °C under 7 V applied bias, which is sufficient to trigger CO2 desorption. The CO2 adsorption capability of the conductive zeolite ink appears to be unaffected by the presence of the conductive particles, meaning a large fraction of the total mass of the structured composite device is functional.

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Performance of metal-functionalized rice husk cellulose for CO2 sorption and CO2/N2 separation

Cited by 24 publications

References 81 publications

New polysulfone microcapsules containing metal oxides and ([BMIM][NTf2]) ionic liquid for CO2 capture

New polysulfone microcapsules containing metal oxides and ([BMIM][NTf2]) ionic liquid for CO2 capture

Imidazolium-based Ionic Liquids Impregnated in Silica and Alumina Supports for CO2 Capture

Intrinsic Thermal Desorption in a 3D Printed Multifunctional Composite CO₂ Sorbent with Embedded Heating Capability

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Performance of metal-functionalized rice husk cellulose for CO2 sorption and CO2/N2 separation

Cited by 24 publications

References 81 publications

New polysulfone microcapsules containing metal oxides and ([BMIM][NTf2]) ionic liquid for CO2 capture

New polysulfone microcapsules containing metal oxides and ([BMIM][NTf2]) ionic liquid for CO2 capture

Imidazolium-based Ionic Liquids Impregnated in Silica and Alumina Supports for CO2 Capture

Intrinsic Thermal Desorption in a 3D Printed Multifunctional Composite CO2 Sorbent with Embedded Heating Capability

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Product

Resources

About

Intrinsic Thermal Desorption in a 3D Printed Multifunctional Composite CO₂ Sorbent with Embedded Heating Capability