Periodic change in absorption maxima due to different chain packing between the bilayers of amphiphiles possessing even and odd numbers of carbons in the hydrophobic chain

Abstract

N-{4-[4-( l0-Trimethylammoniodecyloxy)phenylazo]benzoyl~-~-alanine alkyl ester bromides with n-C, to -CI3 alkyl chains have been newly synthesized. The bilayer aggregates absorbed at 355 nm when the number of carbons was even and at 320 nm when odd. Regardless of whether the number was even or odd, X-ray diffraction patterns suggested a chain penetration structure, where the tail chains in one molecular layer penetrated into the opposite molecular layer, and hence every other azobenzene group was distributed into the opposite layers. However, a remarkable splitting of the CH, scissoring band into 1473 and 1463 cm-' indicated perpendicular alignments of the trans-zigzag planes of the chains containing an even number of carbons, whereas the singlet CH, scissoring band at 1465 cm-' indicated parallel alignments of the planes of the chains containing an odd number of carbons. In accord with the chain packing, when the amphiphiles possess an even number of carbons, the adjacent neighbouring azobenzenes in each layer were arranged perpendicular to each other. The perpendicular location causes a loss of interchromophore interaction, giving a, , , at 355 nm. In contrast, the azobenzenes in the bilayers of the amphiphiles containing an odd number of carbons were all parallel to each other. Because the molecules were tilted above about 60°, a H aggregate should be predominantly formed, which absorbed at 320 nm. In addition, the amphiphiles containing an even number of carbons formed stronger H bonding than those containing an odd number of carbons.

RETRACTED: Bioreactors Based on Enzymes Encapsulated in Photoresponsive Transformable Nanotubes and Nanocoils End‐Capped with Magnetic Nanoparticles

“…The wide‐angle XRD pattern of the nanotubes had 0.46, 0.39, and 0.38 nm peaks, and that of the sheets had 0.41 and 0.38 nm peaks. These profiles strongly suggest lateral packing of oligomethylene spacer chains of the azo‐glycolipid, the so‐called “subcell structure.” The former three peaks were of a triclinic (T // ) type, suggesting that the azo‐glycolipid is packed in a parallel fashion within the monolayer membrane of the nanotubes (Figure ). The latter two peaks were compatible with an orthorhombic (O ⊥ ) type, i.e., the antiparallel molecular packing of the azo‐glycolipid in the sheet (Figure S2, Supporting Information).…”

Polyisocyanides Derived from Tripeptides of Alanine

“…[18] A mixture of l-alanine (10 g, 0.11 mol), n-octanol (17.8 mL, 0.11 mol), and p-toluenesulfonate monohydrate (23.6 g, 0.12 mol) in toluene (625 mL) was refluxed until the amount of water in the Dean-Stark water trap did not increase anymore. The mixture was evaporated to dryness under reduced pressure.…”

Time-controllable roll-up onset of polythiophene sheets into nanotubes that exhibit circularly polarized luminescence

“…Because the wide-angle regions in the XRD patterns of both structures had peaks at 0.41 and 0.38 nm (Fig. S3 †), we assigned the lateral packing of the hydrocarbon chains as an orthorhombic perpendicular type 51,52 (Fig. S4 and S5 †).…”