The acidity constants of 1,4,7-triazacyclononane hydrochloride {(H 3 -[9]-ane-N 3 ) 3+‚3Cl -} at different temperatures and the stability constants of its chelates with Mn(II), Fe(II), Fe(III), Co(II), Co(III), and Cu(II) have been determined pH-metrically in aqueous solution in the presence of 0.1 M KNO 3 at 20 °C and 32 °C. The mole fractions of different species were calculated and discussed. The thermodynamic parameters for the complexes under investigation were also evaluated.