Abstract:The investigation of the internal structure of calcite crystals is a new focus in speleothem science, especially in the range of crystallization temperatures close to 0°C. Recently found calcite spars from Zinnbergschacht Cave of the Franconian Alb (SE Germany) are ideal for multi-method investigation. The elongated calcites (up to 6 cm in length) with three to six lateral faces and basal triangular faces at the ends are observed in collapse-zones in the cave. 230 Th/U-ages of 38.9 ka suggest formation during the periglacial Weichselian, between the Scandinavian and Alpine Glaciations. The δ 18 O and δ 13 C values of the calcite spars vary from -11.18 to -16.11‰ V-PDB and from -4.78 to -6.13‰ V-PDB, respectively. The exceptionally low δ18 O values of these calcites appear to be due to precipitation in pools on ice. The values deviate considerably from those of conventional interglacial speleothems (δ 18 O = -7.21 to -7.55‰, δ 13 C = -9.77 to -10.86‰) and also from true Weichselian cryogenic calcites (composite spherulites and rhombohedral chains with δ 18 O = -15.06 to -18.04‰ and with δ 13 C = -3.52 to -4.13‰). The δ 18 O values of the latter calcites is typical of cryogenesis of calcites with extensive oxygen isotope fractionation (preferred incorporation of 18 O into the co-occurring ice). Thus, the δ 18 O values of the calcites suggest cold conditions up to the beginning of cryogenesis. Cathodoluminescence (CL) and backscattered electrons (BSE) indicate the distribution of impurities within the calcite spars as pigmented triangles surrounded by clear calcite, with a higher density of the triangles in the outer areas. Three hierarchies of triangles can be distinguished by BSE, documenting a filigreed primary structure of the spars. Electron backscatter diffraction (EBSD) reveals a divergent orientation of the triangular subcrystals from the center to the outer corners of the calcites. Thus, their internal structure reflects an example of fascicular optic fibrous calcites (FOFC), frequently discussed in carbonate petrology.Weichselian, cryogenic calcites, fascicular optic fibrous calcite, electron backscatter diffraction, Franconian Alb